Document types usually need a formal description, either a DTD or a Schema. Whilst it is possible to process well-formed XML documents without any such description, trying to create them without one is asking for trouble. A DTD or Schema is used with an XML editor or API interface to guide and control the construction of the document, making sure the right elements go in the right places.
Creating your own document type therefore begins with an analysis of the class of documents you want to describe: reports, invoices, letters, configuration files, credit-card verification requests, or whatever. Once you have the structure correct, you write code to express this formally, using DTD or Schema syntax.